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Ongoing studies at Lehigh University provided some evidence of the desorption of surface adsorbed alkylsiloxane molecules in water. In this particular study, drainage of thin water film is investigated on a glass slide or a silicon wafer, which has circular or rectangular shaped silanized patches. As the water film drains to a thickness of about 10–15 ώm, it ruptures. Examination of the optical interference fringes formed by the draining film as well as rupture dynamics and its scale dependence suggest that the alkylsiloxane molecules desorb more readily from the edges of the hydrophobic patches rather than its center.