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Biointerphases

Journal for Biophysical Chemistry

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Monitoring kinetics of surface initiated atom transfer radical polymerization by quartz crystal microbalance with dissipation

Biointerphases volume 1, pages 35–39 (2006)Cite this article

Abstract

This article reports that the kinetics of surface-initiated atom transfer radical polymerization can be quantified by the quartz crystal microbalance with dissipation (QCM-D) technique. The kinetics of in situ growth of poly(oligoethylene glycol methylmethacrylate) monitored on a gold-coated QCM-D sensor chip revealed that changes in the experimentally observed frequency (ΔF) and dissipation (ΔD) as a function of polymerization time were a function of the initiator density, and that the experimental response could be predicted from a continuum model.

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Authors and Affiliations

  1. Department of Biomedical Engineering, Duke University, 27708-0281, Durham, North Carolina, USA

    Hongwei Ma

  2. Department of Materials, Swiss Federal Institute of Technology, ETH, CH-8093, Zürich, Switzerland

    Marcus Textor

  3. Department of Mechanical Engineering and Materials Science, Duke University, 27708-0300, Durham, North Carolina, USA

    Robert L. Clark

  4. Department of Biomedical Engineering, Duke University, 27708-0281, Durham, North Carolina, USA

    Ashutosh Chilkoti

Authors
  1. Hongwei Ma
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  2. Marcus Textor
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  3. Robert L. Clark
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  4. Ashutosh Chilkoti
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Correspondence to Ashutosh Chilkoti.

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Ma, H., Textor, M., Clark, R.L. et al. Monitoring kinetics of surface initiated atom transfer radical polymerization by quartz crystal microbalance with dissipation. Biointerphases 1, 35–39 (2006). https://doi.org/10.1116/1.2190697

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  • DOI: https://doi.org/10.1116/1.2190697